Di-tert-butyl 2,2′-[9H-fluorene-9,9-diylbis(p-phenyleneoxy)]diacetate

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Di-tert-butyl 2,2′-[9H-fluorene-9,9-diylbis(p-phenyl­ene­oxy)]diacetate

In the title mol-ecule, C(37)H(38)O(6), the non-fused C atom belonging to the five-membered ring of the fluorene system is connected to two p-phenyl-ene rings, the rings opening up the C(ar-yl)-C-C(ar-yl) angle to 113.1 (1)°. The four-atom -O-CH(2)-C(=O)-O- chain between the p-phenyl-ene ring and the tert-butyl group assumes a more regular W-shaped conformation for one substituent [O-C-C-C tors...

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In the title compound, C(29)H(30)N(2), the dihedral angle between the mean planes of the carbazole and the quinoline systems is 52.41 (6)°. Mol-ecules are linked into dimers by pairs of inter-molecular C-H⋯N hydrogen bonds and into a three-dimensional network by C-H⋯π inter-actions.

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9-(4-Bromo­phen­yl)-3,6-di-tert-butyl-9H-carbazole

The asymmetric unit of the title compound, C(26)H(28)BrN, contains two independent mol-ecules in which the carbazole rings are almost planar, with r.m.s. deviations of 0.0212 (1) and 0.0229 (1) Å. The dihedral angles between the carbazole ring system and the pendent benzene ring are 60.5 (1) and 56.3 (1)° in the two mol-ecules. In the crystal, mol-ecules are linked into chains along the b axis ...

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4,5-Dibromo-2,7-di-tert-butyl-9,9-dimethyl-9H-thioxanthene

In the title compound, C(23)H(28)Br(2)S, the thioxanthene unit is twisted, showing a dihedral angle of 29.3 (5)° between the benzene rings. When projected along [001], the packing shows two types of channels. The crystal studied was a racemic twin.

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9-n-Butyl-9,9′-bi[9H-fluorene]

In the title compound, C(30)H(26), the dihedral angle between the two fluorene ring systems is 61.75 (4)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810022579